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Palladium Plating
Typical pH: 7 to 9
Temperature: Room temperature
Agitation: Light to aggressive, depending on type of bath and
process--rack, barrel or high-speed.
In-Tank Filtration: As with gold baths, continuous filtration is
standard procedure to remove particulates that could cause cosmetic or structural
problems.
Carbon Treatment: As needed
Pump Material of Construction: CPVC often specified. Polypropylene
is excellent and sometimes preferred, particularly for ultra-high-purity
applications.
Commonly Used Filter Cartridges: Most customers start with the FK20
or FK10 Poly-Spun Disposables or the PMCA or PMCAB Permacore Magnum Reusables in
the required length. Depending on the solids generated, it may be
desirable to use finer cartridges (lower micron rating) to remove smaller
particles.
Palladium-Tin Activator (for Printed Circuit Industry)
Typical pH: less than 2
Temperature: Room temperature to 100 F (38 C)
Agitation: Mild
In-Tank Filtration: In-tank filtration removes precipitated
palladium particles that reduce activator efficiency.
Carbon Treatment: None
Pump Material of Construction: CPVC commonly specified.
Polypropylene also excellent.
Commonly Used Filter Cartridges: Most customers start with the FK50
or FK20 Poly-Spun Disposables or the PMCA Permacore Magnum Reusables in
the required length. Depending on the solids generated, it may be
desirable to use finer cartridges to remove smaller particles.
Permanganate
Typical pH: Highly alkaline
Temperature: 175 to 190 F (79 to 88 C)
Agitation: Mild to moderate
In-Tank Filtration: Most users do not even attempt to use in-tank
filtration in this powerful deoxidizer because it rapidly attacks plastics, including polypropylene filter cartridges. However, stainless
steel in-tank pumps are sometimes used to circulate the bath, promoting uniform
temperature, and/or to pump solution through chemical or electrolytic
regeneration systems located outside the tank.
Carbon Treatment: None
Pump Material of Construction: 316L stainless steel is the only choice available from Flo King. It usually holds up well in most permanganate solutions, but should still be inspected periodically for
degradation, particularly at welds. (Note: Most suppliers recommend
titanium tanks or liners for permanganate, but Flo King pumps are not available in titanium.)
Commonly Used Filter Cartridges: Again, most filter cartridges
degrade rapidly in permanganate. Any attempts to filter are normally
short-term only. The only other alternative is a special-order Flo King
stainless-steel filter cartridge, which, while very expensive, is
cleanable, reusable, and lasts indefinitely.
Special Notes: Because this can be a harsh environment, the pump must be mounted in a well-ventilated location for maximum motor life. The pump must not be installed in front of the ventilation exhaust, as this will expose the motor to a continuous draft of fumes. In addition, some users brush on the pump motor a thin layer of caustic-resistant liquid maskant to prevent perforation corrosion of the motor housing.
Phosphate, Iron
Typical pH: 3.5 to 6
Temperature: 90 to 140 F (32 to 60 C)
Agitation: Moderate to aggressive
In-Tank Filtration: For low-sludging formulations, in-tank
filtration can maintain bath cleanliness, reduce dumping frequency, cut
down on nozzle clogging in spray-washer operations, and improve coating
quality. However, some iron phosphate baths generate high volumes of
sludge, making filtration impractical due to rapid clogging,
changing, and disposing of filter cartridges.
Carbon Treatment: Rare, if ever
Pump Material of Construction: CPVC is commonly specified.
However, at the higher temperature range, polypropylene is generally
considered superior because it is less prone to brittleness.
Commonly Used Filter Cartridges: Some users select the coarsest
available disposable filter cartridges for high-throughput iron phosphate
tanks that generate a fair amount of solids. The most popular are the FK75 (75-micron)
and FK50 (50-micron) Poly-Spun disposable cartridges. For reusables, most iron phosphaters select the
relatively coarse PMCXC (75-micron) and PMCXF (30-micron) Super Magnum
blankets, although the PMCA or finer Magnum blankets can also be used if
smaller particles must be removed.
Special Notes: Where the iron phosphate bath is part of an
automated spray-washer system, it is necessary to install the Flo King
unit in the reservoir tank. In these cases, users typically
fashion a hole or hinged-lid arrangement in the sheet-metal tank cover.
The cutaway is large enough to introduce the Flo King pump body and filter
cartridges, but small enough that the motor base and motor sit on top of
the tank cover.
Phosphate, Zinc or Manganese
Typical pH: 1.8 to 3.2
Temperature: Zinc phosphate, 120 to 180 F (49 to 83 C);
Manganese phosphate, 180 to 190 F (82 to 88 C)
Agitation: Mild to moderate
In-Tank Filtration: Unless the tank is very small, the sludge generated by these baths is
generally so voluminous that in-tank filtration is totally impractical. In
addition, to further complicate matters, the precipitated solids are a
lot like hardened concrete. Most users just periodically decant the
bath and shovel out the sludge. However, some users install an in-tank
pump exclusively to circulate the bath (no filters attached) for temperature and coating uniformity.
Carbon Treatment: None
Pump Material of Construction: Stainless steel is often the only
material that will survive in these solutions at the higher temperature
ranges. A small number of users have specified CPVC or polypropylene
in the lower-temperature zinc phosphate baths.
Commonly Used Filter Cartridges: As stated above, attempts to use
in-tank filtration on these solutions are generally futile, unless perhaps
the tank is very small and the solids manageable. In these cases, use the coarsest
available
disposable filter cartridges in the appropriate length. One candidate is the FK75 (75-micron) Poly-Spun Disposable.
Special Notes: Because this can be a harsh environment, the pump must be mounted in a well-ventilated location for maximum motor life. The pump must not be installed in front of the ventilation exhaust, as this will expose the motor to a continuous draft of fumes. In addition, some users brush on the pump motor a thin layer of acid-resistant liquid maskant to prevent perforation corrosion of the motor housing.
Platinum Plating
Typical pH: 2 to 12
Temperature: 165 to 185 F (74 to 85 C)
Requirements generally the same as for gold plating baths.
Rhodium Plating
Typical pH: less than 1
Temperature: 104 to 130 F (40 to 54 C)
Requirements generally the same as for gold plating baths.
Rinses, Water
Typical pH: N/A
Temperature: Room temperature to hot
Agitation: Mild to aggressive
In-Tank Filtration: Some users filter periodically to remove
dragged-in materials; others filter continuously to reduce dumping and
therefore minimize water consumption.
Carbon Treatment: Can reduce frequency of dumps and water
consumption by removing cloudiness associated with dragged-in organics.
May reduce staining on parts.
Pump Material of Construction: CPVC often specified. Polypropylene
is also excellent.
Commonly Used Filter Cartridges: Most customers start with the FK50
or FK20 Poly-Spun Disposables or the PMCA Permacore Magnum Reusables in
the required length. Depending on the solids generated, it may be
desirable to use finer cartridges (lower micron rating) to remove smaller
particles.
Ruthenium Plating
Typical pH: 1.5 to 2.5
Temperature: 150 to 170 F (66 to 77 C)
Requirements generally the same as for gold plating baths.
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